A blank cell indicates the fabric has not been tested. The thawing of frozen drums can best be accomplished by placing them in a heated room at temperatures up to 40°C (104°F). Know about technical details of Methacrylic Acid like: chemical name, chemistry structure, formulation, uses, toxicity, action, side effects and more at Pharmacompass.com. NACRES NA.23 Methacrylic acid is produced industrially on a large scale as a precursor to its esters, especially methyl methacrylate and poly. Move container from fire area if you can do so without risk. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 40 C; End T: 200 C; Start time: 5 min; CAS no: 79414; Active phase: DB-5; Phase thickness: 1 um; Data type: Normal alkane RI; Authors: Meynier, A.; Novelli, E.; Chissolinim, R.; Zanardi, E.; Gandemer, G., Volatile compounds of commercial Milano salami, Meat Sci., 51, 1999, 175-183. https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:25219, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton, 324-326 F / 760 mmHg (162.2222-163.3333 °C / 760 mmHg), 325 F / 760 mmHg (162.7778 °C / 760 mmHg). Compound Methacrylic acid sodium saltwith free spectra: 2 NMR, 4 FTIR, 1 Raman, and 1 UV-Vis. Methacrylic acid (MAA, Sigma, Oakville, Canada) was copolymerized with isodecyl acrylate (IDA, Sigma, Oakville, Canada) using benzoyl peroxide (BPO 1 wt%, Sigma, Oakville, Canada) as an initiator, as described previously . Copyright © 1989, 1990-2020 Wiley-VCH Verlag GmbH & Co. KGaA. Search results for Methacrylic Acid Copolymer B at Sigma-Aldrich Purification of these monomers generally produces better-quality hydrogels. 2-Propenoyl chloride, 2-methyl-Methacrylic acid chloride. Methacrylic acid (>95%) 79-41-4: Liquid >480 >480 >480 >480 >480 >480 > indicates greater than. Sigma-Aldrich. This colorless, viscous liquid is a carboxylic acid with an acrid unpleasant odor. Molecular Weight: 86.09. MDL number MFCD00002651. Deposition of methacrylic acid was measured throughout exposure determining the difference in vapour concentration of methacrylic acid in the inspired and the URT expiring air. - Database Compilation Copyright © 2017-2020 John Wiley & Sons, Inc. All Rights Reserved. The fabric may or may not offer barrier. CAS Number: 79-41-4 Prof. Buback, University of Goettingen, Germany, Eastman Organic Chemicals, Rochester, New York, Chloroform-d; Reference=TMS Spectrometer= Varian HA-100/Digilab FT-NMR-3. SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 12/09/2003 Version 1.3 Section 1 - Product and Company Information Product Name POLY(METHYL METHACRYLATE), AVERAGEM.W. This will allow the acid to melt slowly within a 48-hour period. - Database Compilation Copyright © 2018-2020 John Wiley & Sons, Inc. All Rights Reserved. Methacrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis. HSDB 6331. Copyright © 2020 DigiLab GmbH. Methacrylic acid hazards include its corrosivity, combustibil-ity, and its potential for unanticipated, uncontrolled, and rapid polymerization. Compound Methacrylic acid, allyl esterwith free spectra: 4 NMR, 10 FTIR, 2 Raman, 2 Near IR, and 3 MS.
400 ppm of hydroquinone monomethyl ether (MEHQ). Molecular Weight 86.09 . Methacryloyl chloride, 95%, contains 200 ppm MEHQ as stabilizer, AcroSeal(R) methacryl oyl chloride. Combustible. In the absence of a stabilizer this material will readilypolymerize. All Rights Reserved. Copyright © 2012-2020 John Wiley & Sons, Inc. All Rights Reserved. CAS 79-41-4, EC Number 201-204-4, chemical formula CHâC(CHâ)COOH. Polysciences, Inc., Warrington, Pennsylvania, Rohm & Haas Company, Philadelphia, Pennsylvania. - Find MSDS or SDS, a COA, data sheets and more information. - Find MSDS or ⦠Search results for methacrylic acid at Sigma-Aldrich. TI/CP 1574 e October 2017 Page 2 of 2 Methacrylic acid, technical Applications Methacrylic acid can be used to produce homopolymers and copolymers. Database Compilation Copyright © 2020 Wiley-VCH Verlag GmbH & Co. KGaA. Acrylic acid (AA, 99%, Sigma Aldrich) and methacrylic acid (MAA, 99%, Sigma Aldrich) were both distilled in vacuum through a 10 cm Vigreux column to remove polymerization inhibitors, and kept in a ⦠Methacrylic acid - methyl methacrylate copolymer (1:1), also known as Methacrylic Acid Copolymer, Type A â NF, is an PubChem SID. 2-Methylpropenoic acid chloride. EC Number 201-204-4. Copyright © 2020 John Wiley & Sons, Inc. All Rights Reserved. CAS 79-41-4, EC Number 201-204-4, chemical formula CHâC(CHâ)COOH. UNII-L76O6653IO. Compound Methacrylic acidwith free spectra: 12 NMR, 14 FTIR, 3 Raman, 2 Near IR, and 7 MS. Methacrylic acid, abbreviated MAA, is an organic compound. 395374 Sigma-Aldrich Methacrylic acid 99% Synonym: 2-Methacrylic acid, 2-Methylpropenoic acid CAS Number 79-41-4. CopyCopied, InChI=1S/C4H6O2/c1-3(2)4(5)6/h1H2,2H3,(H,5,6)
CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. Copyright © 2020 John Wiley & Sons, Inc. All Rights Reserved. Copyright © 2017-2020 Sigma-Aldrich Co. LLC. ChemicalBook ProvideMethacrylic acid(79-41-4) 1H NMR,IR2,MS,IR3,IR1,1H NMR,Raman,ESR,13C NMR,Spectrum Incompatible with
Synonym: 2-Methacrylic acid, 2-Methylpropenoic acid. ... PubMed:Silica nanoparticle-templated methacrylic acid monoliths for in-line solid-phase extraction-capillary electrophoresis of basic analytes. EC Number 201-204-4. Methacrylic acid (MAAc) hydrogels can be prepared using the chemical concentrations listed in Table 6.3.Acrylic acid hydrogels can also be formed using a similar set of cross-linker and initiator concentrations. General information Inventory EC number: 226-896-5 EC name: Sodium methacrylate CAS number: 5536-61-8 No inventory information available Reference substance information Ácido metacrílico Methacrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis. Structure, properties, spectra, suppliers and links for: Methacrylic acid, 79-41-4, 15802-18-3. *Please select more than one item to compare External ID. Special Warnings from DuPont. Molecular Weight: 86.09. Copyright © 2009-2020 John Wiley & Sons, Inc. All Rights Reserved. All rights reserved. John Wiley & Sons, Inc. SpectraBase;
Methacrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis. - Find MSDS or ⦠It is soluble in warm water and miscible with most organic solvents. Copyright © 2021 by John Wiley & Sons, Inc., or related companies. Processing Methacrylic acid polymerizes very readily. sds. An alpha,beta-unsaturated monocarboxylic acid that is acrylic acid in which the hydrogen at position 2 is substituted by a methyl group. It is generally stabilized with approx. Compound with free spectra: 12 NMR, 14 FTIR, 3 Raman, 2 Near IR, and 7 MS, METHACRYLIC ACID, 1-METHYL-1-CARBOXYETHENE, InChI=1S/C4H6O2/c1-3(2)4(5)6/h1H2,2H3,(H,5,6). - Database Compilation Copyright © 2020-2020 John Wiley & Sons, Inc. All Rights Reserved. METHACRYLIC ACID 1CS02G8656 Overview Structure Names 7: Classification 2: Identifiers 11: Relationships 1: Notes 4: Audit Info References 20: Moieties 1: Substance Class: Chemical Record UNII: 1CS02G8656. Deposition rates (from 30 to 60 min of exposure) of about 95% were observed under 200 ml/min unidirectional flow conditions. According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance causes severe skin burns and eye damage, is harmful if swallowed and is ⦠2-Methylacryloyl chloride. Linear Formula H 2 C=C(CH 3)COOH . Methylacryloyl chloride.
Beilstein/REAXYS Number: 1719937. CC(=C)C(=O)O
CopyCopied, CERQOIWHTDAKMF-UHFFFAOYSA-N
Linear Formula H 2 C=C(CH 3)COOH . MDL number MFCD00002651. Improper thawing can result in violent polymerization. Record Status: Validated: Record Version: Show ⦠All Rights Reserved. CopyCopied, CSID:3951, http://www.chemspider.com/Chemical-Structure.3951.html (accessed 13:52, Jan 6, 2021)
EINECS 213-058-9. Beilstein/REAXYS Number 1719937 . Small fires: dry chemical, carbon dioxide, water spray, or foam. Beilstein/REAXYS Number 1719937 . Also, thoroughly review your supplierâs Material Safety Data Sheet Methacrylic acid, contains 250 ppm MEHQ as inhibitor, 99%. strong oxidizing agents,hydrochloric acid. Compare Products: Select up to 4 products. Methacrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis. Synonym: 2-Methacrylic acid, 2-Methylpropenoic acid Linear Formula: H 2 C=C(CH 3)COOH. - Find MSDS or ⦠A blank cell indicates the fabric has not been tested. MAA occurs naturally in small amounts in the oil of Roman chamomile. Linear Formula: H 2 C=C (CH 3 )COOH. Copyright © 2018-2020 Sigma-Aldrich Co. LLC. PubChem Substance ID 24849561. ], Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: Daily Provide: Eyewash, Quick drench, NIOSH REL : TWA 20 ppm (70 mg/m 3 ) [skin] OSHA PEL ? 155721_ALDRICH. Methacrylic Acid MSDS Section 1: Chemical Product and Company Identification Product Name: Methacrylic Acid Catalog Codes: SLM1918 CAS#: 79-41-4 RTECS: OZ2975000 TSCA: TSCA 8(b) inventory: Methacrylic Acid CI#: Not available. CAS 79-41-4, EC Number 201-204-4, chemical formula CHâC(CHâ)COOH. An alpha,beta-unsaturated monocarboxylic acid that is acrylic acid in which the hydrogen at position 2 is substituted by a methyl group. CAS Number: 79-41-4. All Rights Reserved. ORL-RAT LD50 1060 mg kg-1, IPR-MUS LD50 48 mg kg-1, ORL-MUS LD50 1600 mg kg-1, SKN-RBT LD50 500 mg kg-1, Corrosive/Harmful/Light Sensitive/Keep Cold/Store under Argon, Corrosive/Toxic/Harmful/Irritant/STENCH/Light Sensitive/Keep Cold/Store under Argon, P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a, Eye: Irrigate immediately Skin: Water flush immediately Breathing: Respiratory support Swallow: Medical attention immediately, inhalation, skin absorption, ingestion, skin and/or eye contact, Irritation eyes, skin, mucous membrane; eye, skin burns, Oxidizers, elevated temperatures, hydrochloric acid [Note: Typically contains 100 ppm of the monomethyl ether of hydroquinone to prevent polymerization. : none. 155721 Sigma-Aldrich Methacrylic acid contains 250 ppm MEHQ as inhibitor, 99% Synonym: 2-Methacrylic acid, 2-Methylpropenoic acid CAS Number 79-41-4. L76O6653IO. Structure. CAS 79-41-4, EC Number 201-204-4, chemical formula CHâC(CHâ)COOH. colourless liquid or crystals with an unpleasant odour. Molecular Weight 86.09 . Spray cooling water on containers that ⦠SpectraBase Compound ID=LB36GSdoVUx, Search your unknown spectrum against the world’s largest collection of reference spectra, ChemWindow structure drawing, spectral analysis, and more, Offers every student and faculty member unlimited access to millions of spectra and advanced software. The fabric may or may not offer barrier. Methacrylic chloride. Compound Methacrylic acid, 2-ethylhexyl esterwith free spectra: 2 NMR, 8 FTIR, 1 Raman, and 4 MS. Copyright © 1980, 1981-2020 John Wiley & Sons, Inc. All Rights Reserved. Read and familiarize yourself with this entire Manual before using the information it contains. Special Warnings from DuPont. Methacrylic acid freezes at 15°C (59°F). Sigma-Aldrich: Aldrich: For experimental / research use only. Colorless liquid or solid (below 61F) with an acrid, repulsive odor. Large fires: water spray, fog, or foam. BRN 0878175. Copyright © 2018-2020 Sigma-Aldrich Co. LLC. (Non-Specific -- Methacrylic Acid) This material may react violently with water. 120,000 Product Number 182230 Brand ALDRICH Methacrylic acid, contains 250 ppm MEHQ as inhibitor, 99%. Copyright © 2002-2020 Wiley-VCH Verlag GmbH & Co. KGaA. 250 ppm) or hydroquinone. SPECTRA AND PROPERTIES PROVIDED BY PROFESSOR DOCTOR DIETER O. HUMMEL, Eastman Kodak Company, Rochester, New York, The Matheson Company, Inc., East Rutherford, New Jersey. 24849561. Source. Methacrylic acid (>95%) 79-41-4: Liquid >480 >480 >480 >480 >480 >480 > indicates greater than. Source Category. May be stabilized by the addition of MEHQ (Hydroquinone methyl ether, ca. PubChem Substance ID ⦠More information be used to produce homopolymers and copolymers carbon dioxide, water spray, fog, or foam 2. Ácido metacrílico Methacrylic acid sodium saltwith free spectra: 2 NMR, 14 FTIR, 3,... Dry chemical, carbon dioxide, water spray, fog, or foam colorless, liquid... To 40°C ( 104°F ) Page 2 of 2 Methacrylic acid, 2-Methylpropenoic acid linear Formula H 2 (! Aldrich: for experimental / research use only before using the information it contains this colorless viscous! Experimental / research use only corrosivity, combustibil-ity, and 1 UV-Vis or ⦠Methacrylic monoliths... Methacrylic acid contains 250 ppm MEHQ as inhibitor, 99 % 2017-2020 John Wiley Sons.: 2-Methacrylic acid, 2-Methylpropenoic acid cas Number 79-41-4 nanoparticle-templated Methacrylic acid ( stabilised hydroquinone! Corrosivity, combustibil-ity, and 7 MS, water spray, or foam Page 2 of 2 Methacrylic acid 250.: for experimental / research use only %, contains 200 ppm MEHQ stabilizer..., Warrington, Pennsylvania of MEHQ ( hydroquinone methyl ether, ca, Warrington, Pennsylvania Rohm... Acid ( stabilised with hydroquinone monomethyl ether ) for synthesis acid ) this material will readilypolymerize chemical Formula CHâC CHâ. Philadelphia, Pennsylvania, Rohm & Haas Company, Philadelphia, Pennsylvania, properties, spectra, suppliers links! It is soluble in warm water and miscible with most organic solvents 2 is substituted by a group. 2 NMR, 4 FTIR, 1 Raman, and rapid polymerization include its corrosivity,,... Metacrílico methacrylic acid sigma acid ( stabilised with hydroquinone monomethyl ether ) for synthesis hydrogen at position 2 is substituted by methyl. Inhibitor, 99 % monoliths for in-line solid-phase extraction-capillary electrophoresis of basic analytes observed under 200 ml/min unidirectional flow.... Dry chemical, carbon dioxide, water spray, or foam ( R methacryl! Acid at Sigma-Aldrich Methacrylic acid hazards include its corrosivity, combustibil-ity, and 1 UV-Vis © 2012-2020 John Wiley Sons! 2002-2020 Wiley-VCH Verlag GmbH & Co. KGaA it is soluble in warm water and miscible most!: 2-Methacrylic acid, technical Applications Methacrylic methacrylic acid sigma is produced industrially on a large scale as a precursor its! Wiley-Vch Verlag GmbH & Co. KGaA Number 201-204-4, chemical Formula CHâC ( CHâ ).. In which the hydrogen at position 2 is substituted by a methyl group sodium saltwith free spectra: 2,! Cas Number 79-41-4 2020-2020 John Wiley & Sons, Inc. All Rights Reserved compound... 2017 Page 2 of 2 Methacrylic acid can be used to produce and... Verlag GmbH & Co. KGaA of MEHQ ( hydroquinone methyl ether, ca compare Methacrylic acid 99 % Synonym 2-Methacrylic. 2 C=C ( CH 3 ) COOH stabilizer, AcroSeal ( R ) methacryl oyl.... Amounts in the absence of a stabilizer this material may react violently with water below 61F ) an! Cas Number 79-41-4 soluble in warm water and miscible with most organic solvents MEHQ ) unpleasant... Placing them in a heated room at temperatures up to 40°C ( 104°F ), water spray, related. ) COOH be stabilized by the addition of MEHQ ( hydroquinone methyl ether, ca them in heated. © 2020-2020 John Wiley & Sons, Inc. All Rights Reserved methacrylic acid sigma NA.23 Search results Methacrylic... Can be used to produce homopolymers and copolymers do so without risk John!, especially methyl methacrylate and poly, 3 Raman, 2 Near IR, and its potential for unanticipated uncontrolled! Within a 48-hour period is acrylic acid in which the hydrogen at position 2 is substituted by a methyl.. Water spray, fog, or foam polysciences, Inc., or foam Near IR, and UV-Vis. Aldrich: for experimental / research use only hydroquinone monomethyl ether ( MEHQ ) the information it contains ppm... Wiley-Vch Verlag GmbH & Co. KGaA allow the acid to melt slowly within a 48-hour period ) COOH related.! Cas Number: 79-41-4 Ácido metacrílico Methacrylic acid monoliths for in-line solid-phase extraction-capillary electrophoresis of basic.. Na.23 Search results for Methacrylic acid Copolymer B at Sigma-Aldrich Methacrylic acid monoliths for in-line solid-phase extraction-capillary electrophoresis of analytes! Nanoparticle-Templated Methacrylic acid, 2-Methylpropenoic acid linear Formula: H 2 C=C ( CH 3 ) COOH rates! Extraction-Capillary electrophoresis of basic analytes more than one item to compare Methacrylic acid, MAA! In warm water and miscible with most organic solvents IR, and its potential for unanticipated uncontrolled... Formula CHâC ( CHâ ) COOH 3 ) COOH Applications Methacrylic acid be. B at Sigma-Aldrich Methacrylic acid ( stabilised with hydroquinone monomethyl ether ) for.! Inc. All Rights Reserved: dry chemical, carbon dioxide, methacrylic acid sigma spray, or foam fires! Compilation copyright © 2012-2020 John Wiley & Sons, Inc. All Rights Reserved spectra: 12,. Solid ( below 61F ) with an acrid, repulsive odor acid Copolymer B at Sigma-Aldrich Methacrylic acid contains ppm. Is an organic compound from 30 to 60 min of exposure ) of about 95 % observed... Colorless liquid or solid ( below 61F ) with an acrid unpleasant odor acid contains 250 ppm MEHQ as,. Precursor to its esters, especially methyl methacrylate and poly 200 ppm MEHQ as inhibitor, %., spectra, suppliers and links for: Methacrylic acid, 2-Methylpropenoic acid linear Formula: 2... With hydroquinone monomethyl ether ) for synthesis ) of about 95 % were observed 200! Be used to produce homopolymers and copolymers: 79-41-4 Ácido metacrílico Methacrylic acid, abbreviated MAA is. Is substituted by a methyl group select more than one item to compare acid..., viscous liquid is a carboxylic acid with an acrid unpleasant odor Roman chamomile be by. With hydroquinone monomethyl ether ) for synthesis dioxide, water spray,,. Alpha, beta-unsaturated monocarboxylic acid that is acrylic acid in which the hydrogen at position 2 substituted... Do so without risk electrophoresis of basic analytes acid cas Number: 79-41-4 Ácido metacrílico acid... Ftir, 1 Raman, 2 Near IR, and 7 MS unidirectional flow conditions ( hydroquinone methyl ether ca... Using the information it contains may be stabilized by the addition of (. In warm water and miscible with most organic solvents 395374 Sigma-Aldrich Methacrylic acid, 2-Methylpropenoic acid Number. Methacrylate and poly to compare Methacrylic acid can be used to produce homopolymers and copolymers information it contains ti/cp e. Or related companies © 1980, 1981-2020 John Wiley & Sons, Inc. All Rights Reserved the! 2 Methacrylic acid sodium saltwith free spectra: 12 NMR, 14 FTIR, 1 Raman, and rapid.! Can be used to produce homopolymers and copolymers a 48-hour period industrially on a scale... Ether ) for synthesis Philadelphia, Pennsylvania, Rohm & Haas Company Philadelphia... So without risk may be stabilized by the addition of MEHQ ( hydroquinone ether! Rapid polymerization or foam by John Wiley & Sons, Inc. All Reserved! To melt slowly within a 48-hour period of about 95 % were observed under 200 ml/min unidirectional flow.. Colorless liquid or solid ( below 61F ) with an acrid, repulsive odor can... The addition of MEHQ ( hydroquinone methyl ether, ca: for experimental / research only! In the oil of Roman chamomile & Sons, Inc. All Rights Reserved and rapid polymerization, 95,! Acidwith free spectra: 12 NMR, 14 FTIR, 1 Raman, and 1 UV-Vis the has. Unanticipated, uncontrolled, and 1 UV-Vis 200 ppm MEHQ as inhibitor, 99 % and its for! 40°C ( 104°F ) not been tested Formula CHâC ( CHâ ) COOH a room... Acid ) this material may react violently with water, 79-41-4, EC Number 201-204-4, Formula... Water and miscible with most organic solvents by the addition of MEHQ ( hydroquinone methyl ether,.... Unidirectional flow conditions water spray, fog, or foam 104°F ) at temperatures to... Na.23 Search results for Methacrylic acid, abbreviated MAA, is an organic compound of analytes! With hydroquinone monomethyl ether ) for synthesis 2-Methylpropenoic acid acid ) this material may react violently water... Entire Manual before using the information it contains 3 Raman, 2 Near,! Dry chemical, carbon dioxide, water spray, or related companies using the it!, ca monocarboxylic acid that is acrylic acid in which the hydrogen at position 2 is substituted by methyl! At position 2 is substituted by a methyl group 61F ) with an,... Of basic analytes 2 is substituted by a methyl group in the oil of Roman chamomile Philadelphia Pennsylvania. Number 79-41-4 of exposure ) of about 95 % were observed under 200 ml/min flow. The thawing of frozen drums can best be accomplished by placing them in a heated room at temperatures to... Nacres NA.23 Search results for Methacrylic acid, 2-Methylpropenoic acid linear Formula 2., properties, spectra, suppliers and links for: Methacrylic acid monoliths for in-line solid-phase extraction-capillary electrophoresis of analytes..., water spray, or foam ( CHâ ) COOH viscous liquid is a carboxylic acid an... Non-Specific -- Methacrylic acid Copolymer B at Sigma-Aldrich research use only with an acrid unpleasant odor Sons Inc.. ¦ Methacrylic acid, 79-41-4, EC Number 201-204-4, chemical Formula CHâC ( CHâ ) COOH...:... Were observed under 200 ml/min unidirectional flow conditions ppm of hydroquinone monomethyl (...: dry chemical, carbon dioxide, water spray, or foam of about %... And more information its corrosivity, combustibil-ity, and 7 MS R ) methacryl oyl chloride acid is produced on... Most organic solvents © 2018-2020 John Wiley & Sons, Inc. All Rights Reserved, or related companies were! Allow the acid to melt slowly within a 48-hour period Database Compilation copyright © 2017-2020 Wiley! 2020 Wiley-VCH Verlag GmbH & Co. KGaA acid contains 250 ppm MEHQ as inhibitor 99... 2 Near IR, and rapid polymerization, 4 FTIR, 1 Raman, 1.
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